高分子材料

张群朝

张群朝，男，博士，教授，硕士生导师，出生于1976年08月，1999年毕业于武汉大学化学系高分子化工专业，获工学学士学位；2007年毕业于中南民族大学永利娱高ylg060net有机化学专业，获理学硕士学位；2011年毕业于武汉大学化学与分子科学学院高分子化学与物理专业，获理学博士学位。现担任《有机硅材料》杂志编委，研究方向是有机硅单体和聚合物的设计、制备与表征研究，主要研究领域为硅烷特种单体的设计与开发、有机硅改性高分子材料、有机硅水性复合材料和硅烷/纳米无机复合材料。目前已经发表SCI论文30多篇，承担国家级项目4项，省级重大项目8项，横向课题研究项目30项，授权发明专利20项，获得省级科技奖励3项，武汉市科技奖励2项。

联系电话： 027-88661879

Email: zhangqc1976@hubu.edu.cn

一、代表性发表论文：

[1]Zhao Y. T., Hao T. H., Wu W., Meng Y., Cao X. W., Zhang Q. C.*, She W.*, You J., Shi D. A., Jiang T., A novel moisture-controlled siloxane-modified hyperbranched waterborne poly-urethane for durable superhydrophobic coatings [J]. Applied Surface Science, 2022, 152446-152454.

[2] Huang, D., Li, D., Mo, K. W., Xu R., Huang Y. N., Cui Y. D., Zhang Q. C.*, Chang C. Y., Top-down fabrication of biodegradable multilayer tunicate cellulose films with controlled mechanical properties [J]. Cellulose, 2021, 28: 10415–10424.

[3] Huang W. J., Huang J. S., Yu B., Meng Y., Cao X. W., Zhang Q. C.*, Wei W.*, Shi D. A., Jiang T., Robert K. Y. Li, Facile preparation of phosphorus containing hyperbranched polysiloxane grafted graphene oxide hybrid toward simultaneously enhanced flame retardancy and smoke suppression of thermoplastic polyurethane nanocomposites [J]. Composites Part A: Applied Science and Manufacturing, 2021, 150: 106614-106627.

[4] Cao X. W., Huang J. S., He Y., Hu C. Y., Zhang Q. C.*, Yin X. M., Wu W.*, Robert K.Y. Li, Biodegradable and renewable UV-shielding polylactide composites containing hierarchical structured POSS functionalized lignin [J]. International Journal of Biological Macromolecules, 2021, 188: 323-332.

[5] Yang J. X., She W.*, Zuo W. Q., Lyu K., Zhang Q. C., Rational application of nano-SiO2 in cement paste incorporated with silane: Counterbalancing and synergistic effects [J] Cement and Concrete Composites, 2021, 118: 103959-103969.

[6] Yang J. Y., Shi M. H., Wu W.*, Zhang Q. C.*, You J., Shi D. A., Jiang T., Cross-linked siloxane-based copolymer binder with combined hardness and softness for stable silicon anodes in Li-ion batteries [J]. Journal of Materials Science, 2021, 56(36): 20126-20137.

[7] Zhang Q., Zhang G. Z., You J., Zhang Q. C. *, Tao H. Z. , Highly Penetrable Silicone Emulsion for Water-Repellent Concrete with Reserved Surface Recoatability [J]. Journal of Wuhan University of Technology-Mater. Sci. Ed. 2022, 37(1): 58-65.

[8] Yang K. H., Zhou Y. S., Wang Z. B., Li M. J, Shi D. A., Wang X. B., Jiang T., Zhang Q. C.*, Ding B. B.*, You J.*, Pseudosolvent Intercalator of Chitin: Self-Exfoliating into Sub-1 nm Thick Nanofibrils for Multifunctional Chitinous Materials [J]. Advanced Materials, 2021,33(10): 2007596-2007604.

[9] Tang Q., Wang K., Ren X. M., Zhang Q. C. *, Lei W. W., Jiang T., Shi D. A. *, Preparation of porous antibacterial polyamide 6 (PA6) membrane with zinc oxide (ZnO) nanoparticles selectively localized at the pore walls via reactive extrusion [J]. Science of The Total Environment, 2020,715: 137018-137025.

[10] Wu Y. L., She W., Shi D. A., Jiang T., Hao T. H., Liu J., Zhang Q. C.*, You J., Robert K.Y. Li, An extremely chemical and mechanically durable siloxane bearing copolymer coating with self-crosslinkable and anti-icing properties [J]. Composites Part B: Engineering, 2020,195: 108031-108039.

[11] She W.*, Zheng Z. H., Zhang Q. C., Zuo W. Q., Yang J. X., Zhang Y. S., Zheng L., Hong J. X., Miao C. W., Predesigning matrix-directed super-hydrophobiz-ation and hierarchical strengthening of cement foam[J]. Cement and Concrete Research, 2020, 131: 106029-106039.

[12] Zhao H., She W., Shi D. A., Zhang Q. C. *, Robert K. Y. Li, Polyurethane/POSS nanocomposites for superior hydrophobicity and high ductility [J]. Composites Part B: Engineering, 2019, 177: 107441-107448.

[13] He Y., Yang Y., Ji X. X., Zhang Q. C., Jiang T., Shi H. C.*, Luan S. F., Robert K.Y. Li, Shi D. A.*, Preparation of polymer electrolyte membranes with continuous PEG channel via the fusion of self-assembled polycyclooctene-graft-polyethylene glycol copolymer micelles [J]. Journal of Membrane Science, 2019, 572: 358-364.

[14] Zhang S. X., Wu X. L., Hao T. H., Hu G. H., Jiang T., Zhang Q. C.*, Zhao H., Structure design, fabrication and property investigation of water-based polyesters with notable surface hydrophilicity [J]. New Journal of Chemistry, 2018, 42: 20015-20023.

[15] She W., Wang X. H., Miao C. W., Zhang Q. C., Zhang Y. S., Yang J. X., Hong J. X., Biomimetic superhydrophobic surface of concrete: Topographic and chemical modification assembly by direct spray [J]. Construction and Building Materials, 2018, 181: 347-357.

[16] Zhao H., Huang D., Hao T. H., Hu G. H., Ye G. B., Jiang T., Zhang Q. C.*, Synthesis and Investigation of Well-defined Silane Terminated and Segmented Waterborne Hybrid Polyurethanes [J]. New Journal of Chemistry, 2017, 41(17): 9268-9275.

[17] Zhao H., Hao T. H., Hu G. H., Shi D. A., Huang D., Jiang T., Zhang Q. C.*, Preparation and Characterization of Polyurethanes with Cross- Linked Siloxane in the Side Chain by Sol-Gel Reactions [J]. Materials, 2017, 10: 247-261.

[18] Feng Y. C., Zhao H., Hao T. H., Hu G. H., Zhang Q. C.*, Jiang T., Effects of Poly(cyclohexanedimethylene terephthal-ate) on Microstructures, Crystallization Behavior and Properties of the Poly(ester ether) Elastomers [J]. Materials, 2017, 10(7): 694-708.

[19] Hao T. H., Liu X. B., Hu G. H., Jiang T.*, Zhang Q. C.*, Preparation and characterization of polyurethane/POSS hybrid aqueous dispersions from mono-amino substituted POSS [J]. Polymer Bulletin, 2017,74(2):517-529

[20] Hao T. H., Zhang C., Hu G. H., Jiang T., Zhang Q. C.*, Effects of co-hard segments on the microstructure and prop-erties thermoplastic poly(ether-ester) elastomers [J]. Journal of Applied Polymer Science, 2016, 133(17):43337-43344.

[21] Sun Z.G., Liu B., Huang S. Q.*, Wu J., Zhang Q. C., Facile fabrication of superhydrophobic coating based on polysiloxane emulsion [J], Progress in Organic Coatings, 2017, 102: 131-137.

[22] Zhang Q. C.*, Hu J. K., Gong S. L., Preparation and characterization of aqueous polyurethane dispersions with well-defined soft segments [J]. Journal of Applied Polymer Science, 2011, 122(5): 3064-70.

[23] 彭迪，张群朝*，徐慧，等.水捕获法制备MQ硅树脂[J].有机硅材料. 2019, 33(3): 171 -175.

[24] 张国铮，施德安，张群朝*，等.混凝土用硅氧烷防护与修复材料的研究进展[J].混凝土与水泥制品，2018,10:18-23.

[25] 孙丽丽，黄霁，张群朝*，等.水溶性聚醚改性硅油的制备及其对硅橡胶表面亲水改性的研究[J].有机硅材料. 2018, 32(5):382-387.

[26] 肖俊平，冯琼华，张群朝*，等.氨基烷基共聚型低聚硅氧烷的制备及表征[J].有机硅材料.2016, 30(6):440-444.

二．代表性授权发明专利

[1] 张群朝, 李国荣, 蒋涛, 谢亦富, 杨金鑫, 王秋娣, 廖有为.一种主链含硅氧烷结构单元的聚脲共聚物及其制备方法，授权号：ZL201410056649.

[2] 张群朝, 李国荣, 蒋涛, 谢亦富, 杨金鑫, 王秋娣, 廖有为.一种聚脲专用耐抗污的有机硅低聚物及其制备方法，授权号：ZL201410069078.

[3] 张群朝, 蒋涛, 任小明, 余双, 莫甲新.一种零VOC光聚合丙烯酸酯压敏胶组合物及制备方法，授权号：ZL201310315517.

[4] 赵辉, 任小明,蒋涛, 张刚申, 张群朝, 周威, 董兵海, 郝同辉.用工业废弃物二水钛石膏制备高强α-半水钛石膏的方法，授权号：ZL201410138164.

[5] 张群朝, 吴小峰, 王德才, 陈国民, 一种高相容低粘度的硅氧烷复合改性异氰酸酯三聚体及其制备方法，中国，ZL201010594728.

[6] 吴小峰，张群朝，王德才，陈国民，一种有机硅改性高官能度的多异氰酸酯及其水性化方法，中国，ZL201010594642.

[7] 张群朝，王德才，含硅烷或功能聚硅氧烷改性的异氰酸酯类三聚体及其制备方法，中国，ZL200710052179.

[8] 张群朝，王德才，刘胜，王新建，含异氰酸酯烷基硅烷或异氰酸酯烷氧基硅烷的制备方法，中国，ZL200610019723.

[9] 张群朝，蒋涛，任小明，余双，莫甲新，一种零VOC光聚合丙烯酸酯压敏胶组合物及制备方法，中国，ZL201310315517.

[10] 李进，张群朝，王德才，双硅烷偶联剂及其制备方法，中国，ZL201110029964.

[11] 张群朝，陈国民，王德才，吴小峰，亲水性硅氧烷改性异氰酸酯类三聚体及其制备方法，中国，ZL201110008448.

[12] 吴小峰，张群朝，王德才，基于异氰酸酯基烷基烷氧基硅烷水溶性体系结构及其制备方法，中国，ZL200910272560.